CobaltMaghrebV1, Main, Exploration, bibRecord, 000625

Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde

Identifieur interne : 000625 ( Main/Exploration ); précédent : 000624; suivant : 000626

Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde

Auteurs : Lakhdar Sibous [Algérie] ; Embarek Bentouhami [Algérie] ; Amor Maïza [Algérie] ; Gilles M. Bouet [France] ; MUSTAYEEN AHMED KHAN [France]

Source :

Journal of solution chemistry [ 0095-9782 ] ; 2010.

RBID : Pascal:10-0289681

Descripteurs français

Pascal (Inist)
- Synthèse, Caractérisation, Electrochimie, Complexe de cobalt, Cobalt II, Complexe de nickel, Nickel II, Complexe de cadmium, Cadmium II, Voltammétrie cyclique, Condensation, Base Schiff, Chlorure.
Wicri :
- topic : Condensation.

English descriptors

KwdEn :
- Cadmium II, Cadmium complex, Characterization, Chlorides, Cobalt II, Cobalt complex, Condensation, Cyclic voltammetry, Electrochemistry, Nickel II, Nickel complex, Schiff base, Synthesis.

Abstract

The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H₂L1 or H₂L2. The bases served as tetradentate ligands to coordinate Co^II, Ni^II and Co^II chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, ¹H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.

Affiliations:

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Le document en format XML

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, Ni<sup>II</sup>
 and Cd<sup>II</sup>
 Complexes with N<sub>2</sub>
0<sub>2</sub>
 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</title>
<author><name sortKey="Sibous, Lakhdar" sort="Sibous, Lakhdar" uniqKey="Sibous L" first="Lakhdar" last="Sibous">Lakhdar Sibous</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, Characterization and Electrochemical Behavior of Co<sup>II</sup>
, Ni<sup>II</sup>
 and Cd<sup>II</sup>
 Complexes with N<sub>2</sub>
0<sub>2</sub>
 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde</title>
<author><name sortKey="Sibous, Lakhdar" sort="Sibous, Lakhdar" uniqKey="Sibous L" first="Lakhdar" last="Sibous">Lakhdar Sibous</name>
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<author><name sortKey="Bentouhami, Embarek" sort="Bentouhami, Embarek" uniqKey="Bentouhami E" first="Embarek" last="Bentouhami">Embarek Bentouhami</name>
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<s3>DZA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<country>Algérie</country>
<wicri:noRegion>Sétif 19000</wicri:noRegion>
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<author><name sortKey="Maiza, Amor" sort="Maiza, Amor" uniqKey="Maiza A" first="Amor" last="Maïza">Amor Maïza</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Département de Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université Ferhat Abbas</s1>
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<s3>DZA</s3>
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<country>Algérie</country>
<wicri:noRegion>Sétif 19000</wicri:noRegion>
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<author><name sortKey="Bouet, Gilles M" sort="Bouet, Gilles M" uniqKey="Bouet G" first="Gilles M." last="Bouet">Gilles M. Bouet</name>
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<settlement type="city">Angers</settlement>
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</author>
<author><name sortKey="Mustayeen Ahmed Khan" sort="Mustayeen Ahmed Khan" uniqKey="Mustayeen Ahmed Khan" last="Mustayeen Ahmed Khan">MUSTAYEEN AHMED KHAN</name>
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</author>
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<series><title level="j" type="main">Journal of solution chemistry</title>
<title level="j" type="abbreviated">J. solution chem.</title>
<idno type="ISSN">0095-9782</idno>
<imprint><date when="2010">2010</date>
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<seriesStmt><title level="j" type="main">Journal of solution chemistry</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Cadmium II</term>
<term>Cadmium complex</term>
<term>Characterization</term>
<term>Chlorides</term>
<term>Cobalt II</term>
<term>Cobalt complex</term>
<term>Condensation</term>
<term>Cyclic voltammetry</term>
<term>Electrochemistry</term>
<term>Nickel II</term>
<term>Nickel complex</term>
<term>Schiff base</term>
<term>Synthesis</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Synthèse</term>
<term>Caractérisation</term>
<term>Electrochimie</term>
<term>Complexe de cobalt</term>
<term>Cobalt II</term>
<term>Complexe de nickel</term>
<term>Nickel II</term>
<term>Complexe de cadmium</term>
<term>Cadmium II</term>
<term>Voltammétrie cyclique</term>
<term>Condensation</term>
<term>Base Schiff</term>
<term>Chlorure</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Condensation</term>
</keywords>
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<front><div type="abstract" xml:lang="en">The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4'-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H<sub>2</sub>
L1 or H<sub>2</sub>
L2. The bases served as tetradentate ligands to coordinate Co<sup>II</sup>
, Ni<sup>II</sup>
 and Co<sup>II</sup>
 chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, <sup>1</sup>
H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.</div>
</front>
</TEI>
<affiliations><list><country><li>Algérie</li>
<li>France</li>
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<region><li>Pays de la Loire</li>
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<tree><country name="Algérie"><noRegion><name sortKey="Sibous, Lakhdar" sort="Sibous, Lakhdar" uniqKey="Sibous L" first="Lakhdar" last="Sibous">Lakhdar Sibous</name>
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<country name="France"><region name="Pays de la Loire"><name sortKey="Bouet, Gilles M" sort="Bouet, Gilles M" uniqKey="Bouet G" first="Gilles M." last="Bouet">Gilles M. Bouet</name>
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Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde

Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N202 Donor Ligands Derived from 4,4'-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde

Source :

Descripteurs français

English descriptors

Abstract

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